This shot didn't turn out at all what I was going for. Although I was looking for the sun to burst through the flower pedals, what I wasn't going for was the silloutte effect. I actually wanted to show the color of the flowers against the sky as well as bright orange vase they were in. Owell, maybe next time.
In PS I added an selective color to try to bring out as much color as possible....not much obviously. I also added a contrast layer.
Sunny Flowers....Not Sunflowers: